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The Art of Writing Reasonable Organic Reaction Mechanisms
Buch von Robert B. Grossman
Sprache: Englisch

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Beschreibung
Intended for students of intermediate organic chemistry, this text shows how to write a reasonable mechanism for an organic chemical transformation. The discussion is organized by types of mechanisms and the conditions under which the reaction is executed, rather than by the overall reaction as is the case in most textbooks. The treatment emphasizes unifying principles, showing how common mechanisms link seemingly disparate reactions.

Each chapter discusses common mechanistic pathways and suggests practical tips for drawing them. Worked problems are included in the discussion of each mechanism, and ¿common error alerts¿ are scattered throughout the text to warn readers about pitfalls and misconceptions that bedevil students. Each chapter is capped by a large problem set.

The author has drawn on his own research and the current literature to ensure that appropriate attention is given to topics across the range of modern organic chemistry. The text is unique in its inclusion of a chapter on reactions mediated or catalyzed by transition metals, an area in which mechanistic understanding is now essential. Relatively new topics such as olefin metathesis and cycloaromatization are covered without giving short shrift to more traditional areas such as carbonyl chemistry. The text assumes a basic knowledge of organic chemistry. It can be used either in a formal course or by students working on their own, and will be particularly useful for graduate students studying for qualifying examinations. It will also be useful to students and researchers in biochemistry, pharmacology, and inorganic chemistry.
Intended for students of intermediate organic chemistry, this text shows how to write a reasonable mechanism for an organic chemical transformation. The discussion is organized by types of mechanisms and the conditions under which the reaction is executed, rather than by the overall reaction as is the case in most textbooks. The treatment emphasizes unifying principles, showing how common mechanisms link seemingly disparate reactions.

Each chapter discusses common mechanistic pathways and suggests practical tips for drawing them. Worked problems are included in the discussion of each mechanism, and ¿common error alerts¿ are scattered throughout the text to warn readers about pitfalls and misconceptions that bedevil students. Each chapter is capped by a large problem set.

The author has drawn on his own research and the current literature to ensure that appropriate attention is given to topics across the range of modern organic chemistry. The text is unique in its inclusion of a chapter on reactions mediated or catalyzed by transition metals, an area in which mechanistic understanding is now essential. Relatively new topics such as olefin metathesis and cycloaromatization are covered without giving short shrift to more traditional areas such as carbonyl chemistry. The text assumes a basic knowledge of organic chemistry. It can be used either in a formal course or by students working on their own, and will be particularly useful for graduate students studying for qualifying examinations. It will also be useful to students and researchers in biochemistry, pharmacology, and inorganic chemistry.
Zusammenfassung

Intended for students of intermediate organic chemistry, this text shows how to write a reasonable mechanism for an organic chemical transformation. The discussion is organized by types of mechanisms and the conditions under which the reaction is executed, rather than by the overall reaction. Worked problems are included with each mechanism, and "common error alerts" are strategically placed throughout the text. Each chapter is capped by a large problem set. The author draws on both his own research and the current literature to cover topics across the range of modern organic chemistry. The text includes a chapter on reactions mediated or catalyzed by transition metals, and covers emerging topics without short-changing more traditional material. Assuming a basic knowledge of organic chemistry, the text can be used in a formal course or by students working independently, and will be particularly useful as a study aid for qualifying examinations.

Inhaltsverzeichnis
The Basics.- Polar Reactions under Basic Conditions.- Polar Reactions under Acidic Conditions.- Pericyclic Reactions.- Free-Radical Reactions.- Transition-Metal-Catalyzed and -Mediated Reactions.- Mixed-Mechanism Problems.
Details
Erscheinungsjahr: 2002
Fachbereich: Organische Chemie
Genre: Chemie
Rubrik: Naturwissenschaften & Technik
Medium: Buch
Inhalt: xvi
360 S.
34 s/w Illustr.
360 p. 34 illus.
ISBN-13: 9780387954684
ISBN-10: 0387954686
Sprache: Englisch
Ausstattung / Beilage: HC runder Rücken kaschiert
Einband: Gebunden
Autor: Grossman, Robert B.
Auflage: 2nd ed. 2003
Hersteller: Springer US
Springer New York
Maße: 241 x 160 x 25 mm
Von/Mit: Robert B. Grossman
Erscheinungsdatum: 13.12.2002
Gewicht: 0,723 kg
Artikel-ID: 102579400
Zusammenfassung

Intended for students of intermediate organic chemistry, this text shows how to write a reasonable mechanism for an organic chemical transformation. The discussion is organized by types of mechanisms and the conditions under which the reaction is executed, rather than by the overall reaction. Worked problems are included with each mechanism, and "common error alerts" are strategically placed throughout the text. Each chapter is capped by a large problem set. The author draws on both his own research and the current literature to cover topics across the range of modern organic chemistry. The text includes a chapter on reactions mediated or catalyzed by transition metals, and covers emerging topics without short-changing more traditional material. Assuming a basic knowledge of organic chemistry, the text can be used in a formal course or by students working independently, and will be particularly useful as a study aid for qualifying examinations.

Inhaltsverzeichnis
The Basics.- Polar Reactions under Basic Conditions.- Polar Reactions under Acidic Conditions.- Pericyclic Reactions.- Free-Radical Reactions.- Transition-Metal-Catalyzed and -Mediated Reactions.- Mixed-Mechanism Problems.
Details
Erscheinungsjahr: 2002
Fachbereich: Organische Chemie
Genre: Chemie
Rubrik: Naturwissenschaften & Technik
Medium: Buch
Inhalt: xvi
360 S.
34 s/w Illustr.
360 p. 34 illus.
ISBN-13: 9780387954684
ISBN-10: 0387954686
Sprache: Englisch
Ausstattung / Beilage: HC runder Rücken kaschiert
Einband: Gebunden
Autor: Grossman, Robert B.
Auflage: 2nd ed. 2003
Hersteller: Springer US
Springer New York
Maße: 241 x 160 x 25 mm
Von/Mit: Robert B. Grossman
Erscheinungsdatum: 13.12.2002
Gewicht: 0,723 kg
Artikel-ID: 102579400
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