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The definitive guide to organic coatings, thoroughly revised and updated--now with coverage of a range of topics not covered in previous editions
Organic Coatings: Science and Technology, Fourth Edition offers unparalleled coverageof organic coatings technology and its many applications. Written by three leading industry experts (including a new, internationally-recognized coatings scientist) it presents a systematic survey of the field, revises and updates the material from the previous edition, and features new or additional treatment of such topics as superhydrophobic, ice-phobic, antimicrobial, and self-healing coatings; sustainability, artist paints, and exterior architectural primers. making it even more relevant and useful for scientists and engineers in the field, as well as for students in coatings courses.
The book incorporates up-to-date coverage of recent developments in the field with detailed discussions of the principles underlying the technology and their applications in the development, production, and uses of organic coatings. All chapters in this new edition have been updated to assure consistency and to enable extensive cross-referencing. The material presented is also applicable to the related areas of printing inks and adhesives, as well as areas within the plastics industry.
This new edition
* Completely revises outdated chapters to ensure consistency and to enable extensive cross-referencing
* Correlates the empirical technology of coatings with the underlying science throughout
* Provides expert troubleshooting guidance for coatings scientists and technologists
* Features hundreds of illustrative figures and extensive references to the literature
* A new, internationally-recognized coatings scientist brings fresh perspective to the content.
Providing a broad overview for beginners in the field of organic coatings and a handy reference for seasoned professionals, Organic Coatings: Science and Technology, Fourth Edition, gives you the information and answers you need, when you need them.
Organic Coatings: Science and Technology, Fourth Edition offers unparalleled coverageof organic coatings technology and its many applications. Written by three leading industry experts (including a new, internationally-recognized coatings scientist) it presents a systematic survey of the field, revises and updates the material from the previous edition, and features new or additional treatment of such topics as superhydrophobic, ice-phobic, antimicrobial, and self-healing coatings; sustainability, artist paints, and exterior architectural primers. making it even more relevant and useful for scientists and engineers in the field, as well as for students in coatings courses.
The book incorporates up-to-date coverage of recent developments in the field with detailed discussions of the principles underlying the technology and their applications in the development, production, and uses of organic coatings. All chapters in this new edition have been updated to assure consistency and to enable extensive cross-referencing. The material presented is also applicable to the related areas of printing inks and adhesives, as well as areas within the plastics industry.
This new edition
* Completely revises outdated chapters to ensure consistency and to enable extensive cross-referencing
* Correlates the empirical technology of coatings with the underlying science throughout
* Provides expert troubleshooting guidance for coatings scientists and technologists
* Features hundreds of illustrative figures and extensive references to the literature
* A new, internationally-recognized coatings scientist brings fresh perspective to the content.
Providing a broad overview for beginners in the field of organic coatings and a handy reference for seasoned professionals, Organic Coatings: Science and Technology, Fourth Edition, gives you the information and answers you need, when you need them.
The definitive guide to organic coatings, thoroughly revised and updated--now with coverage of a range of topics not covered in previous editions
Organic Coatings: Science and Technology, Fourth Edition offers unparalleled coverageof organic coatings technology and its many applications. Written by three leading industry experts (including a new, internationally-recognized coatings scientist) it presents a systematic survey of the field, revises and updates the material from the previous edition, and features new or additional treatment of such topics as superhydrophobic, ice-phobic, antimicrobial, and self-healing coatings; sustainability, artist paints, and exterior architectural primers. making it even more relevant and useful for scientists and engineers in the field, as well as for students in coatings courses.
The book incorporates up-to-date coverage of recent developments in the field with detailed discussions of the principles underlying the technology and their applications in the development, production, and uses of organic coatings. All chapters in this new edition have been updated to assure consistency and to enable extensive cross-referencing. The material presented is also applicable to the related areas of printing inks and adhesives, as well as areas within the plastics industry.
This new edition
* Completely revises outdated chapters to ensure consistency and to enable extensive cross-referencing
* Correlates the empirical technology of coatings with the underlying science throughout
* Provides expert troubleshooting guidance for coatings scientists and technologists
* Features hundreds of illustrative figures and extensive references to the literature
* A new, internationally-recognized coatings scientist brings fresh perspective to the content.
Providing a broad overview for beginners in the field of organic coatings and a handy reference for seasoned professionals, Organic Coatings: Science and Technology, Fourth Edition, gives you the information and answers you need, when you need them.
Organic Coatings: Science and Technology, Fourth Edition offers unparalleled coverageof organic coatings technology and its many applications. Written by three leading industry experts (including a new, internationally-recognized coatings scientist) it presents a systematic survey of the field, revises and updates the material from the previous edition, and features new or additional treatment of such topics as superhydrophobic, ice-phobic, antimicrobial, and self-healing coatings; sustainability, artist paints, and exterior architectural primers. making it even more relevant and useful for scientists and engineers in the field, as well as for students in coatings courses.
The book incorporates up-to-date coverage of recent developments in the field with detailed discussions of the principles underlying the technology and their applications in the development, production, and uses of organic coatings. All chapters in this new edition have been updated to assure consistency and to enable extensive cross-referencing. The material presented is also applicable to the related areas of printing inks and adhesives, as well as areas within the plastics industry.
This new edition
* Completely revises outdated chapters to ensure consistency and to enable extensive cross-referencing
* Correlates the empirical technology of coatings with the underlying science throughout
* Provides expert troubleshooting guidance for coatings scientists and technologists
* Features hundreds of illustrative figures and extensive references to the literature
* A new, internationally-recognized coatings scientist brings fresh perspective to the content.
Providing a broad overview for beginners in the field of organic coatings and a handy reference for seasoned professionals, Organic Coatings: Science and Technology, Fourth Edition, gives you the information and answers you need, when you need them.
Über den Autor
FRANK N. JONES is a consultant and an Emeritus Professor at Eastern Michigan University, where he was Director, of the National Science Foundation Industry/University Cooperative Research Center in Coatings. Previously he was Professor and Chair of the Department of Polymers and Coatings at North Dakota State University.
MARK E. NICHOLS is currently Technical Leader, Paint and Corrosion Research at the Ford Motor Company and the Editor-in-Chief of the Journal of Coatings Technology and Research. He is the recipient of the Industry Excellence Award from the ACA as well as a Roon Award.
SOCRATES PETER PAPPAS is a consultant. Previously he was Corporate Scientist at Kodak Polychrome Graphics, Director of Chemical Imaging at Polychrome Corporation, Scientific Fellow at Loctite Corporation, and Professor at North Dakota State University in the Departments of Chemistry, as well as Polymers and Coatings.
Inhaltsverzeichnis
Chapter 1. Introduction to Coatings
1.1. Definitions and Scope
1.2. Types of Coatings
1.3. Composition of Coatings
1.4. Coating History
1.5. Commercial Considerations
Chapter 2. Polymerization and Film Formation
2.1. Polymers
2.1.1. Molecular Weight (MW)
2.1.2. Morphology and Glass Transition Temperature, Tg
2.2. Polymerization
2.2.1. Chain-Growth Polymerization; Living Polymerizations
2.2.2. Step-Growth Polymerization
2.3. Film Formation
2.3.1. Film Formation by Solvent Evaporation from Solutions of Thermoplastic Binders
2.3.2. Film Formation from Solutions of Thermosetting Resins
2.3.3. Film Formation by Coalescence of Polymer Particles
Chapter 3. Flow
3.1. Shear Flow
3.2. Types of Shear Flow
3.3. Determination of Shear Viscosity
3.3.1. Capillary Viscometers
3.3.2. Rheometers
3.3.3. Rotating Disk Viscometers
3.3.4. Bubble Viscometers
3.3.5. Efflux Cups
3.3.6. Paddle Viscometers
3.4. Shear Viscosity of Resin Solutions
3.4.1. Temperature Dependence of Viscosity
3.4.2. Dilute Polymer Solution Viscosity
3.4.3. Concentrated Polymer Solution Viscosity
3.5. Viscosity of Liquids with Dispersed Phases
3.5.1. Thickeners for Latex Coatings
3.6. Other Modes of Flow
3.6.1. Turbulent Flow
3.6.2. Normal Force Flow
3.6.3. Extensional Flow
Chapter 4. Mechanical Properties
4.1. Introduction
4.2. Basic Mechanical Properties
4.2.1 Glass Transition Temperature (Tg)
4.2.2 Viscoelasticity
4.2.3. Dynamic Mechanical Behavior
4.3. Formulation, Process, and Structure Effects
4.4. Fracture Mechanics
4.5. Abrasion, Scratch, and Mar Resistance
4.5.1. Abrasion Resistance
4.5.2. Scratch and Mar Resistance
4.6. Measurement of Mechanical Properties
4.7. Tests of Coatings on Substrates
4.7.1. Field Exposure Tests
4.7.2. Laboratory Simulation Tests
4.7.3. Empirical Tests
Chapter 5. Exterior Durability
5.1. Photoinitiated Oxidative Degradation
5.2. Photostabilization
5.2.1. UV Absorbers and Excited State Quenchers
5.2.2. Antioxidants
5.2.3. Hindered Amine Light Stabilizers
5.2.4. Pigmentation Effects
5.3. Degradation of Chlorinated Resins
5.4. Hydrolytic Degradation
5.5. Other Modes of Failure on Exterior Exposure
5.6. Testing for Exterior Durability
5.6.1. Natural Weathering
5.6.2. Accelerated Outdoor Exposure
5.6.3. Accelerated Laboratory Weathering Devices
5.6.4. Analysis of Coating Changes During Weathering
5.7. Service Life Prediction
Chapter 6. Adhesion
6.1. Mechanisms of Adhesion
6.1.1. Surface Mechanical Effects on Adhesion
6.1.2. Relationships Between Wetting and Adhesion
6.2. Mechanical Stresses and Adhesion
6.3. Adhesion to Metal Surfaces
6.3.1. Conversion Coating and Pretreatment of Metal Substrates
6.4. Characterization of Surfaces
6.5. Organic Chemical Treatment of Substrates to Enhance Adhesion
6.6. Covalent Bonding to Glass and Metal Substrates
6.7. Adhesion to Plastics and to Coatings
6.8. Testing for Adhesion
Chapter 7. Corrosion Protection by Coatings
7.1. Corrosion Basics
7.2. Corrosion of Uncoated Steel
7.3. Corrosion Protection of Metals
7.3.1. Passivation--Anodic Protection
7.3.2. Cathodic Protection
7.3.3. Barrier Protection and Inhibition
7.4. Corrosion Protection by Intact Coatings
7.4.1. Critical Factors
7.4.2. Adhesion for Corrosion Protection
7.4.3. Factors Affecting Oxygen and Water Permeability
7.5. Corrosion Protection by Nonintact Films
7.5.1. Minimizing Growth of Imperfections--Cathodic Delamination
7.5.2. Primers with Passivating Pigments
7.5.3. Cathodic Protection by Zinc-Rich Primers
7.5.4. Smart Corrosion Control Coatings
7.6. Evaluation and Testing
Chapter 8. Acrylic Resins
8.1. Thermoplastic Acrylic Resins
8.2. Thermosetting Acrylic Resins
8.2.1. Hydroxy-Functional Acrylics
8.2.2. Acrylics Having Other Functional Groups
8.3. Water-Reducible Thermosetting Acrylic Resins
Chapter 9. Latexes
9.1. Emulsion Polymerization
9.1.1. Raw Materials for Emulsion Polymerization
9.1.2. Emulsion Polymerization Variables
9.1.3. Sequential Polymerization
9.2. Acrylic Latexes
9.3. Vinyl Ester Latexes
9.4. Thermosetting Latexes
9.4.1. One-Package Thermosetting Latex Coatings that Require Baking for Cure
9.4.2. Two-package (2K) Thermosetting Latex Coatings that do not Require Baking
9.4.3. One-package Thermosetting Latex Coatings that do not Require Baking
Chapter 10. Polyester Resins
10.1. Hydroxy-Terminated Polyesters for Conventional Solids Coatings
10.1.1. Selection of Polyols
10.1.2. Selection of Polyacids
10.2. Polyester Resins for High Solids Coatings
10.3. Carboxylic Acid-Terminated Polyester Resins
10.4. Carbamate-Functional Polyester Resins
10.5. Water-Reducible Polyester Resins
10.6. Polyester Resins for Powder Coatings
Chapter 11. Amino Resins
11.1. Synthesis of Melamine-Formaldehyde Resins
11.1.1. The Methylolation Reaction
11.1.2. The Etherification Reaction
11.1.3. Self-Condensation Reactions
11.2. Types of MF Resins
11.3. MF Polyol Reactions in Coatings
11.3.1. Catalysis of MF-Polyol Reactions
11.3.2. Kinetics and Mechanism of MF-Polyol Co-condensation
11.3.3. Package Stability Considerations
11.3.4. MF Resin Reactions with Carboxylic Acids, Urethanes, Carbamates, and Malonate-Blocked Isocyanates
11.4. Other Amino Resins
11.4.1. Urea-Formaldehyde Resins
11.4.2. Benzoguanamine-Formaldehyde Resins
11.4.3. Glycoluril-Formaldehyde Resins
11.4.4. Poly(meth)acrylamide-Formaldehyde Resins
Chapter 12. Polyurethanes and Polyisocyanates
12.1. Reactions of Isocyanates
12.2. Kinetics of Isocyanate Reactions with Alcohols
12.2.1. Noncatalyzed Reactions
12.2.2. Catalysts
12.2.3. Interrelationships in Catalysis
12.3. Isocyanates Used in Coatings
12.3.1. Aromatic Isocyanates
12.3.2. Aliphatic Isocyanates
12.4. Two Package (2K) Solventborne Urethane Coatings
12.4.1. 2K Polyurea Coatings
12.5. Blocked Isocyanates
12.5.1. Principles of Blocking and Deblocking
12.5.2. Blocking Groups
12.5.3. Catalysis of Blocked Isocyanate Coatings
12.6. Moisture-Curable Urethane Coatings
12.7. Waterborne Polyurethane Coatings
12.7.1. Polyurethane Dispersions
12.7.2. Acrylic/Polyurethane Blends and Hybrid Dispersions
12.7.2.1. Cross-linked PUD/Acrylate Systems
12.7.3. 2K Waterborne Urethanes
12.8. Hydroxy-Terminated Polyurethanes
Chapter 13. Epoxy and Phenolic Resins
13.1. Epoxy Resins
13.1.1. Bisphenol A Epoxy Resins
13.1.2. Other Epoxy Resins
13.2. Amine Cross-linked Epoxy Resins
13.2.1. Pot Life and Cure Time Considerations
13.2.2. Toxicity and Stoichiometric Considerations
13.2.3. Graininess and Blushing
13.2.4. Tg Considerations
13.2.5. Other Formulating Considerations
13.2.6. Waterborne Epoxy-Amine Systems
13.3. Other Cross-Linking Agents for Epoxy Resins
13.3.1. Phenols
13.3.2. Carboxylic Acids and Anhydrides
13.3.3. Hydroxyl Groups
13.3.4. Mercaptans
13.3.5. Homopolymerization
13.4. Water-Reducible Epoxy/Acrylic Graft Copolymers; Epoxy Acrylic Hybrids
13.5. Epoxy Resin Phosphate Esters
13.6. Phenolic Resins
13.6.1. Resole Phenolic Resins
13.6.2. Novolac Phenolic Resins
13.6.3. Ether Derivatives of Phenolic Resins
Chapter 14. Drying Oils
14.1. Compositions of Natural Oils
14.2. Autoxidation and Cross-Linking
14.2.1. Nonconjugated Drying Oils
14.2.2. Catalysis of Autoxidation and Cross-Linking
14.2.3. Conjugated Drying Oils
14.3. Synthetic and Modified Drying Oils
14.3.1. Heat Bodied Oils, Blown Oils, and Dimer Acids
14.3.2. Varnishes
14.3.3. Synthetic Conjugated Oils
14.3.4. Esters of Higher Functionality Polyols
14.3.5. Maleated Oils
14.3.6. Vinyl-Modified Oils
Chapter 15. Alkyd Resins
15.1. Oxidizing Alkyds
15.1.1. Monobasic Acid Selection
15.1.2. Polyol Selection
15.1.3. Dibasic Acid Selection
15.2. High Solids Oxidizing Alkyds
15.3. Water-Borne Oxidizing Alkyds
15.3.1. Water-Reducible Alkyds
15.3.2. Alkyd Emulsions
15.4. Nonoxidizing Alkyds
15.5. Synthetic Procedures for Alkyd Resins
15.5.1. Synthesis from Oils or Fatty Acids
15.5.2. Process Variations
15.6. Modified Alkyds
15.7. Uralkyds and Other Autoxidizable Urethanes
15.7.1. Uralkyds
15.7.2. Autoxidizable Polyurethane Dispersions
15.8. Epoxy Esters
Chapter 16. Silicon Derivatives
16.1. Silicones
16.1.1. Silicone Rubbers and Resins
16.1.2. Modified Silicone Resins
16.1.3. Silicone-Modified Resins
16.2. Reactive Silanes
16.3. Orthosilicates
16.3.1. Sol-Gel Coatings
Chapter 17. Other Resins and Cross-linkers
17.1. Halogenated Polymers
17.1.1. Solution Grade Thermoplastic Vinyl Chloride Copolymers
17.1.2. Vinyl chloride Dispersion Copolymers
17.1.3. Chlorinated Rubber, Chlorinated Ethylene/Vinyl Acetate Copolymer, and Chlorinated Polyethylene
17.1.4. Fluorinated Polymers
17.2. Cellulose Derivatives Soluble in Organic Solvents
17.2.1. Nitrocellulose
17.2.2. Cellulose Acetobutyrate
17.3. Unsaturated Polyester Resins
17.4. (Meth)acrylated Oligomers
17.5. 2-Hydroxyalkylamide Cross-Linkers
17.6. Acetoacetate Cross-Linking Systems
17.7. Polyaziridine Cross-Linkers
17.8. Polycarbodiimide Cross-Linkers
17.9. Polycarbonates
17.10. Non-Isocyanate Two-Package Binders
17.10.1. Carbamate-Aldehyde Chemistry
17.10.2. Michael Addition Chemistry
17.11. Dihydrazides
Chapter 18. Solvents
18.1. Solvent Composition
18.2. Solubility
18.2.1. Solubility Parameters
18.2.2. Three-Dimensional Solubility Parameters
18.2.3. Other Solubility Theories
18.2.4. Practical Considerations
18.3. Solvent Evaporation Rates
18.3.1. Evaporation of Single Solvents
18.3.2. Relative Evaporation Rates
18.3.3. Evaporation of Mixed Solvents
18.3.4. Evaporation of Solvents from Coating Films
18.3.5. Evaporation of Solvents from High Solids Coatings
18.3.6. Volatile Loss from Waterborne Coatings
18.4. Viscosity Effects
18.5. Flammability
18.6. Other Physical Properties
18.7. Toxic Hazards
18.8. Atmospheric Photochemical Effects
18.9. Regulation of Solvent Emission from Coatings
18.9.1. Determination of VOC
18.9.2. Regulations
Chapter 19. Color and Appearance
19.1....
1.1. Definitions and Scope
1.2. Types of Coatings
1.3. Composition of Coatings
1.4. Coating History
1.5. Commercial Considerations
Chapter 2. Polymerization and Film Formation
2.1. Polymers
2.1.1. Molecular Weight (MW)
2.1.2. Morphology and Glass Transition Temperature, Tg
2.2. Polymerization
2.2.1. Chain-Growth Polymerization; Living Polymerizations
2.2.2. Step-Growth Polymerization
2.3. Film Formation
2.3.1. Film Formation by Solvent Evaporation from Solutions of Thermoplastic Binders
2.3.2. Film Formation from Solutions of Thermosetting Resins
2.3.3. Film Formation by Coalescence of Polymer Particles
Chapter 3. Flow
3.1. Shear Flow
3.2. Types of Shear Flow
3.3. Determination of Shear Viscosity
3.3.1. Capillary Viscometers
3.3.2. Rheometers
3.3.3. Rotating Disk Viscometers
3.3.4. Bubble Viscometers
3.3.5. Efflux Cups
3.3.6. Paddle Viscometers
3.4. Shear Viscosity of Resin Solutions
3.4.1. Temperature Dependence of Viscosity
3.4.2. Dilute Polymer Solution Viscosity
3.4.3. Concentrated Polymer Solution Viscosity
3.5. Viscosity of Liquids with Dispersed Phases
3.5.1. Thickeners for Latex Coatings
3.6. Other Modes of Flow
3.6.1. Turbulent Flow
3.6.2. Normal Force Flow
3.6.3. Extensional Flow
Chapter 4. Mechanical Properties
4.1. Introduction
4.2. Basic Mechanical Properties
4.2.1 Glass Transition Temperature (Tg)
4.2.2 Viscoelasticity
4.2.3. Dynamic Mechanical Behavior
4.3. Formulation, Process, and Structure Effects
4.4. Fracture Mechanics
4.5. Abrasion, Scratch, and Mar Resistance
4.5.1. Abrasion Resistance
4.5.2. Scratch and Mar Resistance
4.6. Measurement of Mechanical Properties
4.7. Tests of Coatings on Substrates
4.7.1. Field Exposure Tests
4.7.2. Laboratory Simulation Tests
4.7.3. Empirical Tests
Chapter 5. Exterior Durability
5.1. Photoinitiated Oxidative Degradation
5.2. Photostabilization
5.2.1. UV Absorbers and Excited State Quenchers
5.2.2. Antioxidants
5.2.3. Hindered Amine Light Stabilizers
5.2.4. Pigmentation Effects
5.3. Degradation of Chlorinated Resins
5.4. Hydrolytic Degradation
5.5. Other Modes of Failure on Exterior Exposure
5.6. Testing for Exterior Durability
5.6.1. Natural Weathering
5.6.2. Accelerated Outdoor Exposure
5.6.3. Accelerated Laboratory Weathering Devices
5.6.4. Analysis of Coating Changes During Weathering
5.7. Service Life Prediction
Chapter 6. Adhesion
6.1. Mechanisms of Adhesion
6.1.1. Surface Mechanical Effects on Adhesion
6.1.2. Relationships Between Wetting and Adhesion
6.2. Mechanical Stresses and Adhesion
6.3. Adhesion to Metal Surfaces
6.3.1. Conversion Coating and Pretreatment of Metal Substrates
6.4. Characterization of Surfaces
6.5. Organic Chemical Treatment of Substrates to Enhance Adhesion
6.6. Covalent Bonding to Glass and Metal Substrates
6.7. Adhesion to Plastics and to Coatings
6.8. Testing for Adhesion
Chapter 7. Corrosion Protection by Coatings
7.1. Corrosion Basics
7.2. Corrosion of Uncoated Steel
7.3. Corrosion Protection of Metals
7.3.1. Passivation--Anodic Protection
7.3.2. Cathodic Protection
7.3.3. Barrier Protection and Inhibition
7.4. Corrosion Protection by Intact Coatings
7.4.1. Critical Factors
7.4.2. Adhesion for Corrosion Protection
7.4.3. Factors Affecting Oxygen and Water Permeability
7.5. Corrosion Protection by Nonintact Films
7.5.1. Minimizing Growth of Imperfections--Cathodic Delamination
7.5.2. Primers with Passivating Pigments
7.5.3. Cathodic Protection by Zinc-Rich Primers
7.5.4. Smart Corrosion Control Coatings
7.6. Evaluation and Testing
Chapter 8. Acrylic Resins
8.1. Thermoplastic Acrylic Resins
8.2. Thermosetting Acrylic Resins
8.2.1. Hydroxy-Functional Acrylics
8.2.2. Acrylics Having Other Functional Groups
8.3. Water-Reducible Thermosetting Acrylic Resins
Chapter 9. Latexes
9.1. Emulsion Polymerization
9.1.1. Raw Materials for Emulsion Polymerization
9.1.2. Emulsion Polymerization Variables
9.1.3. Sequential Polymerization
9.2. Acrylic Latexes
9.3. Vinyl Ester Latexes
9.4. Thermosetting Latexes
9.4.1. One-Package Thermosetting Latex Coatings that Require Baking for Cure
9.4.2. Two-package (2K) Thermosetting Latex Coatings that do not Require Baking
9.4.3. One-package Thermosetting Latex Coatings that do not Require Baking
Chapter 10. Polyester Resins
10.1. Hydroxy-Terminated Polyesters for Conventional Solids Coatings
10.1.1. Selection of Polyols
10.1.2. Selection of Polyacids
10.2. Polyester Resins for High Solids Coatings
10.3. Carboxylic Acid-Terminated Polyester Resins
10.4. Carbamate-Functional Polyester Resins
10.5. Water-Reducible Polyester Resins
10.6. Polyester Resins for Powder Coatings
Chapter 11. Amino Resins
11.1. Synthesis of Melamine-Formaldehyde Resins
11.1.1. The Methylolation Reaction
11.1.2. The Etherification Reaction
11.1.3. Self-Condensation Reactions
11.2. Types of MF Resins
11.3. MF Polyol Reactions in Coatings
11.3.1. Catalysis of MF-Polyol Reactions
11.3.2. Kinetics and Mechanism of MF-Polyol Co-condensation
11.3.3. Package Stability Considerations
11.3.4. MF Resin Reactions with Carboxylic Acids, Urethanes, Carbamates, and Malonate-Blocked Isocyanates
11.4. Other Amino Resins
11.4.1. Urea-Formaldehyde Resins
11.4.2. Benzoguanamine-Formaldehyde Resins
11.4.3. Glycoluril-Formaldehyde Resins
11.4.4. Poly(meth)acrylamide-Formaldehyde Resins
Chapter 12. Polyurethanes and Polyisocyanates
12.1. Reactions of Isocyanates
12.2. Kinetics of Isocyanate Reactions with Alcohols
12.2.1. Noncatalyzed Reactions
12.2.2. Catalysts
12.2.3. Interrelationships in Catalysis
12.3. Isocyanates Used in Coatings
12.3.1. Aromatic Isocyanates
12.3.2. Aliphatic Isocyanates
12.4. Two Package (2K) Solventborne Urethane Coatings
12.4.1. 2K Polyurea Coatings
12.5. Blocked Isocyanates
12.5.1. Principles of Blocking and Deblocking
12.5.2. Blocking Groups
12.5.3. Catalysis of Blocked Isocyanate Coatings
12.6. Moisture-Curable Urethane Coatings
12.7. Waterborne Polyurethane Coatings
12.7.1. Polyurethane Dispersions
12.7.2. Acrylic/Polyurethane Blends and Hybrid Dispersions
12.7.2.1. Cross-linked PUD/Acrylate Systems
12.7.3. 2K Waterborne Urethanes
12.8. Hydroxy-Terminated Polyurethanes
Chapter 13. Epoxy and Phenolic Resins
13.1. Epoxy Resins
13.1.1. Bisphenol A Epoxy Resins
13.1.2. Other Epoxy Resins
13.2. Amine Cross-linked Epoxy Resins
13.2.1. Pot Life and Cure Time Considerations
13.2.2. Toxicity and Stoichiometric Considerations
13.2.3. Graininess and Blushing
13.2.4. Tg Considerations
13.2.5. Other Formulating Considerations
13.2.6. Waterborne Epoxy-Amine Systems
13.3. Other Cross-Linking Agents for Epoxy Resins
13.3.1. Phenols
13.3.2. Carboxylic Acids and Anhydrides
13.3.3. Hydroxyl Groups
13.3.4. Mercaptans
13.3.5. Homopolymerization
13.4. Water-Reducible Epoxy/Acrylic Graft Copolymers; Epoxy Acrylic Hybrids
13.5. Epoxy Resin Phosphate Esters
13.6. Phenolic Resins
13.6.1. Resole Phenolic Resins
13.6.2. Novolac Phenolic Resins
13.6.3. Ether Derivatives of Phenolic Resins
Chapter 14. Drying Oils
14.1. Compositions of Natural Oils
14.2. Autoxidation and Cross-Linking
14.2.1. Nonconjugated Drying Oils
14.2.2. Catalysis of Autoxidation and Cross-Linking
14.2.3. Conjugated Drying Oils
14.3. Synthetic and Modified Drying Oils
14.3.1. Heat Bodied Oils, Blown Oils, and Dimer Acids
14.3.2. Varnishes
14.3.3. Synthetic Conjugated Oils
14.3.4. Esters of Higher Functionality Polyols
14.3.5. Maleated Oils
14.3.6. Vinyl-Modified Oils
Chapter 15. Alkyd Resins
15.1. Oxidizing Alkyds
15.1.1. Monobasic Acid Selection
15.1.2. Polyol Selection
15.1.3. Dibasic Acid Selection
15.2. High Solids Oxidizing Alkyds
15.3. Water-Borne Oxidizing Alkyds
15.3.1. Water-Reducible Alkyds
15.3.2. Alkyd Emulsions
15.4. Nonoxidizing Alkyds
15.5. Synthetic Procedures for Alkyd Resins
15.5.1. Synthesis from Oils or Fatty Acids
15.5.2. Process Variations
15.6. Modified Alkyds
15.7. Uralkyds and Other Autoxidizable Urethanes
15.7.1. Uralkyds
15.7.2. Autoxidizable Polyurethane Dispersions
15.8. Epoxy Esters
Chapter 16. Silicon Derivatives
16.1. Silicones
16.1.1. Silicone Rubbers and Resins
16.1.2. Modified Silicone Resins
16.1.3. Silicone-Modified Resins
16.2. Reactive Silanes
16.3. Orthosilicates
16.3.1. Sol-Gel Coatings
Chapter 17. Other Resins and Cross-linkers
17.1. Halogenated Polymers
17.1.1. Solution Grade Thermoplastic Vinyl Chloride Copolymers
17.1.2. Vinyl chloride Dispersion Copolymers
17.1.3. Chlorinated Rubber, Chlorinated Ethylene/Vinyl Acetate Copolymer, and Chlorinated Polyethylene
17.1.4. Fluorinated Polymers
17.2. Cellulose Derivatives Soluble in Organic Solvents
17.2.1. Nitrocellulose
17.2.2. Cellulose Acetobutyrate
17.3. Unsaturated Polyester Resins
17.4. (Meth)acrylated Oligomers
17.5. 2-Hydroxyalkylamide Cross-Linkers
17.6. Acetoacetate Cross-Linking Systems
17.7. Polyaziridine Cross-Linkers
17.8. Polycarbodiimide Cross-Linkers
17.9. Polycarbonates
17.10. Non-Isocyanate Two-Package Binders
17.10.1. Carbamate-Aldehyde Chemistry
17.10.2. Michael Addition Chemistry
17.11. Dihydrazides
Chapter 18. Solvents
18.1. Solvent Composition
18.2. Solubility
18.2.1. Solubility Parameters
18.2.2. Three-Dimensional Solubility Parameters
18.2.3. Other Solubility Theories
18.2.4. Practical Considerations
18.3. Solvent Evaporation Rates
18.3.1. Evaporation of Single Solvents
18.3.2. Relative Evaporation Rates
18.3.3. Evaporation of Mixed Solvents
18.3.4. Evaporation of Solvents from Coating Films
18.3.5. Evaporation of Solvents from High Solids Coatings
18.3.6. Volatile Loss from Waterborne Coatings
18.4. Viscosity Effects
18.5. Flammability
18.6. Other Physical Properties
18.7. Toxic Hazards
18.8. Atmospheric Photochemical Effects
18.9. Regulation of Solvent Emission from Coatings
18.9.1. Determination of VOC
18.9.2. Regulations
Chapter 19. Color and Appearance
19.1....
Details
| Erscheinungsjahr: | 2017 |
|---|---|
| Fachbereich: | Allgemeines |
| Genre: | Chemie |
| Rubrik: | Naturwissenschaften & Technik |
| Medium: | Buch |
| Inhalt: | 512 S. |
| ISBN-13: | 9781119026891 |
| ISBN-10: | 111902689X |
| Sprache: | Englisch |
| Einband: | Gebunden |
| Autor: |
Jones, Frank N
Nichols, Mark E Pappas, Socrates Peter |
| Auflage: | 4th edition |
| Hersteller: |
Wiley
John Wiley & Sons |
| Maße: | 277 x 218 x 30 mm |
| Von/Mit: | Frank N Jones (u. a.) |
| Erscheinungsdatum: | 02.10.2017 |
| Gewicht: | 1,451 kg |
Über den Autor
FRANK N. JONES is a consultant and an Emeritus Professor at Eastern Michigan University, where he was Director, of the National Science Foundation Industry/University Cooperative Research Center in Coatings. Previously he was Professor and Chair of the Department of Polymers and Coatings at North Dakota State University.
MARK E. NICHOLS is currently Technical Leader, Paint and Corrosion Research at the Ford Motor Company and the Editor-in-Chief of the Journal of Coatings Technology and Research. He is the recipient of the Industry Excellence Award from the ACA as well as a Roon Award.
SOCRATES PETER PAPPAS is a consultant. Previously he was Corporate Scientist at Kodak Polychrome Graphics, Director of Chemical Imaging at Polychrome Corporation, Scientific Fellow at Loctite Corporation, and Professor at North Dakota State University in the Departments of Chemistry, as well as Polymers and Coatings.
Inhaltsverzeichnis
Chapter 1. Introduction to Coatings
1.1. Definitions and Scope
1.2. Types of Coatings
1.3. Composition of Coatings
1.4. Coating History
1.5. Commercial Considerations
Chapter 2. Polymerization and Film Formation
2.1. Polymers
2.1.1. Molecular Weight (MW)
2.1.2. Morphology and Glass Transition Temperature, Tg
2.2. Polymerization
2.2.1. Chain-Growth Polymerization; Living Polymerizations
2.2.2. Step-Growth Polymerization
2.3. Film Formation
2.3.1. Film Formation by Solvent Evaporation from Solutions of Thermoplastic Binders
2.3.2. Film Formation from Solutions of Thermosetting Resins
2.3.3. Film Formation by Coalescence of Polymer Particles
Chapter 3. Flow
3.1. Shear Flow
3.2. Types of Shear Flow
3.3. Determination of Shear Viscosity
3.3.1. Capillary Viscometers
3.3.2. Rheometers
3.3.3. Rotating Disk Viscometers
3.3.4. Bubble Viscometers
3.3.5. Efflux Cups
3.3.6. Paddle Viscometers
3.4. Shear Viscosity of Resin Solutions
3.4.1. Temperature Dependence of Viscosity
3.4.2. Dilute Polymer Solution Viscosity
3.4.3. Concentrated Polymer Solution Viscosity
3.5. Viscosity of Liquids with Dispersed Phases
3.5.1. Thickeners for Latex Coatings
3.6. Other Modes of Flow
3.6.1. Turbulent Flow
3.6.2. Normal Force Flow
3.6.3. Extensional Flow
Chapter 4. Mechanical Properties
4.1. Introduction
4.2. Basic Mechanical Properties
4.2.1 Glass Transition Temperature (Tg)
4.2.2 Viscoelasticity
4.2.3. Dynamic Mechanical Behavior
4.3. Formulation, Process, and Structure Effects
4.4. Fracture Mechanics
4.5. Abrasion, Scratch, and Mar Resistance
4.5.1. Abrasion Resistance
4.5.2. Scratch and Mar Resistance
4.6. Measurement of Mechanical Properties
4.7. Tests of Coatings on Substrates
4.7.1. Field Exposure Tests
4.7.2. Laboratory Simulation Tests
4.7.3. Empirical Tests
Chapter 5. Exterior Durability
5.1. Photoinitiated Oxidative Degradation
5.2. Photostabilization
5.2.1. UV Absorbers and Excited State Quenchers
5.2.2. Antioxidants
5.2.3. Hindered Amine Light Stabilizers
5.2.4. Pigmentation Effects
5.3. Degradation of Chlorinated Resins
5.4. Hydrolytic Degradation
5.5. Other Modes of Failure on Exterior Exposure
5.6. Testing for Exterior Durability
5.6.1. Natural Weathering
5.6.2. Accelerated Outdoor Exposure
5.6.3. Accelerated Laboratory Weathering Devices
5.6.4. Analysis of Coating Changes During Weathering
5.7. Service Life Prediction
Chapter 6. Adhesion
6.1. Mechanisms of Adhesion
6.1.1. Surface Mechanical Effects on Adhesion
6.1.2. Relationships Between Wetting and Adhesion
6.2. Mechanical Stresses and Adhesion
6.3. Adhesion to Metal Surfaces
6.3.1. Conversion Coating and Pretreatment of Metal Substrates
6.4. Characterization of Surfaces
6.5. Organic Chemical Treatment of Substrates to Enhance Adhesion
6.6. Covalent Bonding to Glass and Metal Substrates
6.7. Adhesion to Plastics and to Coatings
6.8. Testing for Adhesion
Chapter 7. Corrosion Protection by Coatings
7.1. Corrosion Basics
7.2. Corrosion of Uncoated Steel
7.3. Corrosion Protection of Metals
7.3.1. Passivation--Anodic Protection
7.3.2. Cathodic Protection
7.3.3. Barrier Protection and Inhibition
7.4. Corrosion Protection by Intact Coatings
7.4.1. Critical Factors
7.4.2. Adhesion for Corrosion Protection
7.4.3. Factors Affecting Oxygen and Water Permeability
7.5. Corrosion Protection by Nonintact Films
7.5.1. Minimizing Growth of Imperfections--Cathodic Delamination
7.5.2. Primers with Passivating Pigments
7.5.3. Cathodic Protection by Zinc-Rich Primers
7.5.4. Smart Corrosion Control Coatings
7.6. Evaluation and Testing
Chapter 8. Acrylic Resins
8.1. Thermoplastic Acrylic Resins
8.2. Thermosetting Acrylic Resins
8.2.1. Hydroxy-Functional Acrylics
8.2.2. Acrylics Having Other Functional Groups
8.3. Water-Reducible Thermosetting Acrylic Resins
Chapter 9. Latexes
9.1. Emulsion Polymerization
9.1.1. Raw Materials for Emulsion Polymerization
9.1.2. Emulsion Polymerization Variables
9.1.3. Sequential Polymerization
9.2. Acrylic Latexes
9.3. Vinyl Ester Latexes
9.4. Thermosetting Latexes
9.4.1. One-Package Thermosetting Latex Coatings that Require Baking for Cure
9.4.2. Two-package (2K) Thermosetting Latex Coatings that do not Require Baking
9.4.3. One-package Thermosetting Latex Coatings that do not Require Baking
Chapter 10. Polyester Resins
10.1. Hydroxy-Terminated Polyesters for Conventional Solids Coatings
10.1.1. Selection of Polyols
10.1.2. Selection of Polyacids
10.2. Polyester Resins for High Solids Coatings
10.3. Carboxylic Acid-Terminated Polyester Resins
10.4. Carbamate-Functional Polyester Resins
10.5. Water-Reducible Polyester Resins
10.6. Polyester Resins for Powder Coatings
Chapter 11. Amino Resins
11.1. Synthesis of Melamine-Formaldehyde Resins
11.1.1. The Methylolation Reaction
11.1.2. The Etherification Reaction
11.1.3. Self-Condensation Reactions
11.2. Types of MF Resins
11.3. MF Polyol Reactions in Coatings
11.3.1. Catalysis of MF-Polyol Reactions
11.3.2. Kinetics and Mechanism of MF-Polyol Co-condensation
11.3.3. Package Stability Considerations
11.3.4. MF Resin Reactions with Carboxylic Acids, Urethanes, Carbamates, and Malonate-Blocked Isocyanates
11.4. Other Amino Resins
11.4.1. Urea-Formaldehyde Resins
11.4.2. Benzoguanamine-Formaldehyde Resins
11.4.3. Glycoluril-Formaldehyde Resins
11.4.4. Poly(meth)acrylamide-Formaldehyde Resins
Chapter 12. Polyurethanes and Polyisocyanates
12.1. Reactions of Isocyanates
12.2. Kinetics of Isocyanate Reactions with Alcohols
12.2.1. Noncatalyzed Reactions
12.2.2. Catalysts
12.2.3. Interrelationships in Catalysis
12.3. Isocyanates Used in Coatings
12.3.1. Aromatic Isocyanates
12.3.2. Aliphatic Isocyanates
12.4. Two Package (2K) Solventborne Urethane Coatings
12.4.1. 2K Polyurea Coatings
12.5. Blocked Isocyanates
12.5.1. Principles of Blocking and Deblocking
12.5.2. Blocking Groups
12.5.3. Catalysis of Blocked Isocyanate Coatings
12.6. Moisture-Curable Urethane Coatings
12.7. Waterborne Polyurethane Coatings
12.7.1. Polyurethane Dispersions
12.7.2. Acrylic/Polyurethane Blends and Hybrid Dispersions
12.7.2.1. Cross-linked PUD/Acrylate Systems
12.7.3. 2K Waterborne Urethanes
12.8. Hydroxy-Terminated Polyurethanes
Chapter 13. Epoxy and Phenolic Resins
13.1. Epoxy Resins
13.1.1. Bisphenol A Epoxy Resins
13.1.2. Other Epoxy Resins
13.2. Amine Cross-linked Epoxy Resins
13.2.1. Pot Life and Cure Time Considerations
13.2.2. Toxicity and Stoichiometric Considerations
13.2.3. Graininess and Blushing
13.2.4. Tg Considerations
13.2.5. Other Formulating Considerations
13.2.6. Waterborne Epoxy-Amine Systems
13.3. Other Cross-Linking Agents for Epoxy Resins
13.3.1. Phenols
13.3.2. Carboxylic Acids and Anhydrides
13.3.3. Hydroxyl Groups
13.3.4. Mercaptans
13.3.5. Homopolymerization
13.4. Water-Reducible Epoxy/Acrylic Graft Copolymers; Epoxy Acrylic Hybrids
13.5. Epoxy Resin Phosphate Esters
13.6. Phenolic Resins
13.6.1. Resole Phenolic Resins
13.6.2. Novolac Phenolic Resins
13.6.3. Ether Derivatives of Phenolic Resins
Chapter 14. Drying Oils
14.1. Compositions of Natural Oils
14.2. Autoxidation and Cross-Linking
14.2.1. Nonconjugated Drying Oils
14.2.2. Catalysis of Autoxidation and Cross-Linking
14.2.3. Conjugated Drying Oils
14.3. Synthetic and Modified Drying Oils
14.3.1. Heat Bodied Oils, Blown Oils, and Dimer Acids
14.3.2. Varnishes
14.3.3. Synthetic Conjugated Oils
14.3.4. Esters of Higher Functionality Polyols
14.3.5. Maleated Oils
14.3.6. Vinyl-Modified Oils
Chapter 15. Alkyd Resins
15.1. Oxidizing Alkyds
15.1.1. Monobasic Acid Selection
15.1.2. Polyol Selection
15.1.3. Dibasic Acid Selection
15.2. High Solids Oxidizing Alkyds
15.3. Water-Borne Oxidizing Alkyds
15.3.1. Water-Reducible Alkyds
15.3.2. Alkyd Emulsions
15.4. Nonoxidizing Alkyds
15.5. Synthetic Procedures for Alkyd Resins
15.5.1. Synthesis from Oils or Fatty Acids
15.5.2. Process Variations
15.6. Modified Alkyds
15.7. Uralkyds and Other Autoxidizable Urethanes
15.7.1. Uralkyds
15.7.2. Autoxidizable Polyurethane Dispersions
15.8. Epoxy Esters
Chapter 16. Silicon Derivatives
16.1. Silicones
16.1.1. Silicone Rubbers and Resins
16.1.2. Modified Silicone Resins
16.1.3. Silicone-Modified Resins
16.2. Reactive Silanes
16.3. Orthosilicates
16.3.1. Sol-Gel Coatings
Chapter 17. Other Resins and Cross-linkers
17.1. Halogenated Polymers
17.1.1. Solution Grade Thermoplastic Vinyl Chloride Copolymers
17.1.2. Vinyl chloride Dispersion Copolymers
17.1.3. Chlorinated Rubber, Chlorinated Ethylene/Vinyl Acetate Copolymer, and Chlorinated Polyethylene
17.1.4. Fluorinated Polymers
17.2. Cellulose Derivatives Soluble in Organic Solvents
17.2.1. Nitrocellulose
17.2.2. Cellulose Acetobutyrate
17.3. Unsaturated Polyester Resins
17.4. (Meth)acrylated Oligomers
17.5. 2-Hydroxyalkylamide Cross-Linkers
17.6. Acetoacetate Cross-Linking Systems
17.7. Polyaziridine Cross-Linkers
17.8. Polycarbodiimide Cross-Linkers
17.9. Polycarbonates
17.10. Non-Isocyanate Two-Package Binders
17.10.1. Carbamate-Aldehyde Chemistry
17.10.2. Michael Addition Chemistry
17.11. Dihydrazides
Chapter 18. Solvents
18.1. Solvent Composition
18.2. Solubility
18.2.1. Solubility Parameters
18.2.2. Three-Dimensional Solubility Parameters
18.2.3. Other Solubility Theories
18.2.4. Practical Considerations
18.3. Solvent Evaporation Rates
18.3.1. Evaporation of Single Solvents
18.3.2. Relative Evaporation Rates
18.3.3. Evaporation of Mixed Solvents
18.3.4. Evaporation of Solvents from Coating Films
18.3.5. Evaporation of Solvents from High Solids Coatings
18.3.6. Volatile Loss from Waterborne Coatings
18.4. Viscosity Effects
18.5. Flammability
18.6. Other Physical Properties
18.7. Toxic Hazards
18.8. Atmospheric Photochemical Effects
18.9. Regulation of Solvent Emission from Coatings
18.9.1. Determination of VOC
18.9.2. Regulations
Chapter 19. Color and Appearance
19.1....
1.1. Definitions and Scope
1.2. Types of Coatings
1.3. Composition of Coatings
1.4. Coating History
1.5. Commercial Considerations
Chapter 2. Polymerization and Film Formation
2.1. Polymers
2.1.1. Molecular Weight (MW)
2.1.2. Morphology and Glass Transition Temperature, Tg
2.2. Polymerization
2.2.1. Chain-Growth Polymerization; Living Polymerizations
2.2.2. Step-Growth Polymerization
2.3. Film Formation
2.3.1. Film Formation by Solvent Evaporation from Solutions of Thermoplastic Binders
2.3.2. Film Formation from Solutions of Thermosetting Resins
2.3.3. Film Formation by Coalescence of Polymer Particles
Chapter 3. Flow
3.1. Shear Flow
3.2. Types of Shear Flow
3.3. Determination of Shear Viscosity
3.3.1. Capillary Viscometers
3.3.2. Rheometers
3.3.3. Rotating Disk Viscometers
3.3.4. Bubble Viscometers
3.3.5. Efflux Cups
3.3.6. Paddle Viscometers
3.4. Shear Viscosity of Resin Solutions
3.4.1. Temperature Dependence of Viscosity
3.4.2. Dilute Polymer Solution Viscosity
3.4.3. Concentrated Polymer Solution Viscosity
3.5. Viscosity of Liquids with Dispersed Phases
3.5.1. Thickeners for Latex Coatings
3.6. Other Modes of Flow
3.6.1. Turbulent Flow
3.6.2. Normal Force Flow
3.6.3. Extensional Flow
Chapter 4. Mechanical Properties
4.1. Introduction
4.2. Basic Mechanical Properties
4.2.1 Glass Transition Temperature (Tg)
4.2.2 Viscoelasticity
4.2.3. Dynamic Mechanical Behavior
4.3. Formulation, Process, and Structure Effects
4.4. Fracture Mechanics
4.5. Abrasion, Scratch, and Mar Resistance
4.5.1. Abrasion Resistance
4.5.2. Scratch and Mar Resistance
4.6. Measurement of Mechanical Properties
4.7. Tests of Coatings on Substrates
4.7.1. Field Exposure Tests
4.7.2. Laboratory Simulation Tests
4.7.3. Empirical Tests
Chapter 5. Exterior Durability
5.1. Photoinitiated Oxidative Degradation
5.2. Photostabilization
5.2.1. UV Absorbers and Excited State Quenchers
5.2.2. Antioxidants
5.2.3. Hindered Amine Light Stabilizers
5.2.4. Pigmentation Effects
5.3. Degradation of Chlorinated Resins
5.4. Hydrolytic Degradation
5.5. Other Modes of Failure on Exterior Exposure
5.6. Testing for Exterior Durability
5.6.1. Natural Weathering
5.6.2. Accelerated Outdoor Exposure
5.6.3. Accelerated Laboratory Weathering Devices
5.6.4. Analysis of Coating Changes During Weathering
5.7. Service Life Prediction
Chapter 6. Adhesion
6.1. Mechanisms of Adhesion
6.1.1. Surface Mechanical Effects on Adhesion
6.1.2. Relationships Between Wetting and Adhesion
6.2. Mechanical Stresses and Adhesion
6.3. Adhesion to Metal Surfaces
6.3.1. Conversion Coating and Pretreatment of Metal Substrates
6.4. Characterization of Surfaces
6.5. Organic Chemical Treatment of Substrates to Enhance Adhesion
6.6. Covalent Bonding to Glass and Metal Substrates
6.7. Adhesion to Plastics and to Coatings
6.8. Testing for Adhesion
Chapter 7. Corrosion Protection by Coatings
7.1. Corrosion Basics
7.2. Corrosion of Uncoated Steel
7.3. Corrosion Protection of Metals
7.3.1. Passivation--Anodic Protection
7.3.2. Cathodic Protection
7.3.3. Barrier Protection and Inhibition
7.4. Corrosion Protection by Intact Coatings
7.4.1. Critical Factors
7.4.2. Adhesion for Corrosion Protection
7.4.3. Factors Affecting Oxygen and Water Permeability
7.5. Corrosion Protection by Nonintact Films
7.5.1. Minimizing Growth of Imperfections--Cathodic Delamination
7.5.2. Primers with Passivating Pigments
7.5.3. Cathodic Protection by Zinc-Rich Primers
7.5.4. Smart Corrosion Control Coatings
7.6. Evaluation and Testing
Chapter 8. Acrylic Resins
8.1. Thermoplastic Acrylic Resins
8.2. Thermosetting Acrylic Resins
8.2.1. Hydroxy-Functional Acrylics
8.2.2. Acrylics Having Other Functional Groups
8.3. Water-Reducible Thermosetting Acrylic Resins
Chapter 9. Latexes
9.1. Emulsion Polymerization
9.1.1. Raw Materials for Emulsion Polymerization
9.1.2. Emulsion Polymerization Variables
9.1.3. Sequential Polymerization
9.2. Acrylic Latexes
9.3. Vinyl Ester Latexes
9.4. Thermosetting Latexes
9.4.1. One-Package Thermosetting Latex Coatings that Require Baking for Cure
9.4.2. Two-package (2K) Thermosetting Latex Coatings that do not Require Baking
9.4.3. One-package Thermosetting Latex Coatings that do not Require Baking
Chapter 10. Polyester Resins
10.1. Hydroxy-Terminated Polyesters for Conventional Solids Coatings
10.1.1. Selection of Polyols
10.1.2. Selection of Polyacids
10.2. Polyester Resins for High Solids Coatings
10.3. Carboxylic Acid-Terminated Polyester Resins
10.4. Carbamate-Functional Polyester Resins
10.5. Water-Reducible Polyester Resins
10.6. Polyester Resins for Powder Coatings
Chapter 11. Amino Resins
11.1. Synthesis of Melamine-Formaldehyde Resins
11.1.1. The Methylolation Reaction
11.1.2. The Etherification Reaction
11.1.3. Self-Condensation Reactions
11.2. Types of MF Resins
11.3. MF Polyol Reactions in Coatings
11.3.1. Catalysis of MF-Polyol Reactions
11.3.2. Kinetics and Mechanism of MF-Polyol Co-condensation
11.3.3. Package Stability Considerations
11.3.4. MF Resin Reactions with Carboxylic Acids, Urethanes, Carbamates, and Malonate-Blocked Isocyanates
11.4. Other Amino Resins
11.4.1. Urea-Formaldehyde Resins
11.4.2. Benzoguanamine-Formaldehyde Resins
11.4.3. Glycoluril-Formaldehyde Resins
11.4.4. Poly(meth)acrylamide-Formaldehyde Resins
Chapter 12. Polyurethanes and Polyisocyanates
12.1. Reactions of Isocyanates
12.2. Kinetics of Isocyanate Reactions with Alcohols
12.2.1. Noncatalyzed Reactions
12.2.2. Catalysts
12.2.3. Interrelationships in Catalysis
12.3. Isocyanates Used in Coatings
12.3.1. Aromatic Isocyanates
12.3.2. Aliphatic Isocyanates
12.4. Two Package (2K) Solventborne Urethane Coatings
12.4.1. 2K Polyurea Coatings
12.5. Blocked Isocyanates
12.5.1. Principles of Blocking and Deblocking
12.5.2. Blocking Groups
12.5.3. Catalysis of Blocked Isocyanate Coatings
12.6. Moisture-Curable Urethane Coatings
12.7. Waterborne Polyurethane Coatings
12.7.1. Polyurethane Dispersions
12.7.2. Acrylic/Polyurethane Blends and Hybrid Dispersions
12.7.2.1. Cross-linked PUD/Acrylate Systems
12.7.3. 2K Waterborne Urethanes
12.8. Hydroxy-Terminated Polyurethanes
Chapter 13. Epoxy and Phenolic Resins
13.1. Epoxy Resins
13.1.1. Bisphenol A Epoxy Resins
13.1.2. Other Epoxy Resins
13.2. Amine Cross-linked Epoxy Resins
13.2.1. Pot Life and Cure Time Considerations
13.2.2. Toxicity and Stoichiometric Considerations
13.2.3. Graininess and Blushing
13.2.4. Tg Considerations
13.2.5. Other Formulating Considerations
13.2.6. Waterborne Epoxy-Amine Systems
13.3. Other Cross-Linking Agents for Epoxy Resins
13.3.1. Phenols
13.3.2. Carboxylic Acids and Anhydrides
13.3.3. Hydroxyl Groups
13.3.4. Mercaptans
13.3.5. Homopolymerization
13.4. Water-Reducible Epoxy/Acrylic Graft Copolymers; Epoxy Acrylic Hybrids
13.5. Epoxy Resin Phosphate Esters
13.6. Phenolic Resins
13.6.1. Resole Phenolic Resins
13.6.2. Novolac Phenolic Resins
13.6.3. Ether Derivatives of Phenolic Resins
Chapter 14. Drying Oils
14.1. Compositions of Natural Oils
14.2. Autoxidation and Cross-Linking
14.2.1. Nonconjugated Drying Oils
14.2.2. Catalysis of Autoxidation and Cross-Linking
14.2.3. Conjugated Drying Oils
14.3. Synthetic and Modified Drying Oils
14.3.1. Heat Bodied Oils, Blown Oils, and Dimer Acids
14.3.2. Varnishes
14.3.3. Synthetic Conjugated Oils
14.3.4. Esters of Higher Functionality Polyols
14.3.5. Maleated Oils
14.3.6. Vinyl-Modified Oils
Chapter 15. Alkyd Resins
15.1. Oxidizing Alkyds
15.1.1. Monobasic Acid Selection
15.1.2. Polyol Selection
15.1.3. Dibasic Acid Selection
15.2. High Solids Oxidizing Alkyds
15.3. Water-Borne Oxidizing Alkyds
15.3.1. Water-Reducible Alkyds
15.3.2. Alkyd Emulsions
15.4. Nonoxidizing Alkyds
15.5. Synthetic Procedures for Alkyd Resins
15.5.1. Synthesis from Oils or Fatty Acids
15.5.2. Process Variations
15.6. Modified Alkyds
15.7. Uralkyds and Other Autoxidizable Urethanes
15.7.1. Uralkyds
15.7.2. Autoxidizable Polyurethane Dispersions
15.8. Epoxy Esters
Chapter 16. Silicon Derivatives
16.1. Silicones
16.1.1. Silicone Rubbers and Resins
16.1.2. Modified Silicone Resins
16.1.3. Silicone-Modified Resins
16.2. Reactive Silanes
16.3. Orthosilicates
16.3.1. Sol-Gel Coatings
Chapter 17. Other Resins and Cross-linkers
17.1. Halogenated Polymers
17.1.1. Solution Grade Thermoplastic Vinyl Chloride Copolymers
17.1.2. Vinyl chloride Dispersion Copolymers
17.1.3. Chlorinated Rubber, Chlorinated Ethylene/Vinyl Acetate Copolymer, and Chlorinated Polyethylene
17.1.4. Fluorinated Polymers
17.2. Cellulose Derivatives Soluble in Organic Solvents
17.2.1. Nitrocellulose
17.2.2. Cellulose Acetobutyrate
17.3. Unsaturated Polyester Resins
17.4. (Meth)acrylated Oligomers
17.5. 2-Hydroxyalkylamide Cross-Linkers
17.6. Acetoacetate Cross-Linking Systems
17.7. Polyaziridine Cross-Linkers
17.8. Polycarbodiimide Cross-Linkers
17.9. Polycarbonates
17.10. Non-Isocyanate Two-Package Binders
17.10.1. Carbamate-Aldehyde Chemistry
17.10.2. Michael Addition Chemistry
17.11. Dihydrazides
Chapter 18. Solvents
18.1. Solvent Composition
18.2. Solubility
18.2.1. Solubility Parameters
18.2.2. Three-Dimensional Solubility Parameters
18.2.3. Other Solubility Theories
18.2.4. Practical Considerations
18.3. Solvent Evaporation Rates
18.3.1. Evaporation of Single Solvents
18.3.2. Relative Evaporation Rates
18.3.3. Evaporation of Mixed Solvents
18.3.4. Evaporation of Solvents from Coating Films
18.3.5. Evaporation of Solvents from High Solids Coatings
18.3.6. Volatile Loss from Waterborne Coatings
18.4. Viscosity Effects
18.5. Flammability
18.6. Other Physical Properties
18.7. Toxic Hazards
18.8. Atmospheric Photochemical Effects
18.9. Regulation of Solvent Emission from Coatings
18.9.1. Determination of VOC
18.9.2. Regulations
Chapter 19. Color and Appearance
19.1....
Details
| Erscheinungsjahr: | 2017 |
|---|---|
| Fachbereich: | Allgemeines |
| Genre: | Chemie |
| Rubrik: | Naturwissenschaften & Technik |
| Medium: | Buch |
| Inhalt: | 512 S. |
| ISBN-13: | 9781119026891 |
| ISBN-10: | 111902689X |
| Sprache: | Englisch |
| Einband: | Gebunden |
| Autor: |
Jones, Frank N
Nichols, Mark E Pappas, Socrates Peter |
| Auflage: | 4th edition |
| Hersteller: |
Wiley
John Wiley & Sons |
| Maße: | 277 x 218 x 30 mm |
| Von/Mit: | Frank N Jones (u. a.) |
| Erscheinungsdatum: | 02.10.2017 |
| Gewicht: | 1,451 kg |
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