Molecular Theory of Fluctuation in Life Ph...

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Sprache: Englisch

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Beschreibung

This book describes molecular processes taking place in living cells, in which water or solvation play essential roles. The molecular processes include conformational stability, fluctuation, relaxation, self-organization, molecular recognition, and chemical reactions. In all those processes, so-called solvation free-energy, and its first and second derivatives with respect to the atomic coordinates of biomolecules play key roles. Such derivatives of the free energy may not be calculated by any method of molecular simulation, because the calculation requires an analytical formula of the solvation free energy as a function of the atomic coordinates of a biomolecule. In this book, the theory is applied to analyze phenomena closely related to the conformational and density fluctuation of biomolecular systems, including the entropy and spectroscopy of both biomolecules and solvents. The theory is further developed to give microscopic expressions to the well-regarded phenomenological theories of chemical reactions, including the Michaelis Menten theory of the enzymatic reaction, and the theory of the electron-transfer reaction by R. Marcus. Also clarified in the book is physical basis of Anfinsen s hypothesis concerning the protein folding. This book is beneficial for graduate students and researchers in the field of life science and technology, especially for those studying pharmaceutical design and biomimetic technology such as artificial enzymes.

Inhaltsverzeichnis

Introduction.- Phenomenological description.- Statistical mechanics of molecular liquids.- Irreversible statistical mechanics of molecular liquids.- Conformational and density fluctuation in biomolecular system.- Chemical reactions of biomolecules in solutions.- Transitions among equilibrium states driven by fluctuations.

Erscheinungsjahr:	2025
Fachbereich:	Theoretische Chemie
Genre:	Chemie , Importe
Rubrik:	Naturwissenschaften & Technik
Medium:	Buch
Inhalt:	x 146 S. 12 s/w Illustr. 19 farbige Illustr. 146 p. 31 illus. 19 illus. in color.
ISBN-13:	9789819633630
ISBN-10:	981963363X
Sprache:	Englisch
Einband:	Gebunden
Autor:	Hirata, Fumio
Hersteller:	Springer Singapore Springer Nature Singapore
Verantwortliche Person für die EU:	Springer Verlag GmbH, Tiergartenstr. 17, D-69121 Heidelberg, juergen.hartmann@springer.com
Maße:	241 x 160 x 15 mm
Von/Mit:	Fumio Hirata
Erscheinungsdatum:	25.04.2025
Gewicht:	0,405 kg

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