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FUNDAMENTALS OF CHEMICAL REACTOR ENGINEERING
A comprehensive introduction to chemical reactor engineering from an industrial perspective
In Fundamentals of Chemical Reactor Engineering: A Multi-Scale Approach, a distinguished team of academics delivers a thorough introduction to foundational concepts in chemical reactor engineering. It offers readers the tools they need to develop a firm grasp of the kinetics and thermodynamics of reactions, hydrodynamics, transport processes, and heat and mass transfer resistances in a chemical reactor.
This textbook describes the interaction of reacting molecules on the molecular scale and uses real-world examples to illustrate the principles of chemical reactor analysis and heterogeneous catalysis at every scale. It includes a strong focus on new approaches to process intensification, the modeling of multifunctional reactors, structured reactor types, and the importance of hydrodynamics and transport processes in a chemical reactor.
With end-of-chapter problem sets and multiple open-ended case studies to promote critical thinking, this book also offers supplementary online materials and an included instructor's manual. Readers will also find:
* A thorough introduction to the rate concept and species conservation equations in reactors, including chemical and flow reactors and the stoichiometric relations between reacting species
* A comprehensive exploration of reversible reactions and chemical equilibrium, including the thermodynamics of chemical reactions and different forms of the equilibrium constant
* Practical discussions of chemical kinetics and analysis of batch reactors, including batch reactor data analysis
* In-depth examinations of ideal flow reactors, CSTR, and plug flow reactor models
Ideal for undergraduate and graduate chemical engineering students studying chemical reactor engineering, chemical engineering kinetics, heterogeneous catalysis, and reactor design, Fundamentals of Chemical Reactor Engineering is also an indispensable resource for professionals and students in food, environmental, and materials engineering.
A comprehensive introduction to chemical reactor engineering from an industrial perspective
In Fundamentals of Chemical Reactor Engineering: A Multi-Scale Approach, a distinguished team of academics delivers a thorough introduction to foundational concepts in chemical reactor engineering. It offers readers the tools they need to develop a firm grasp of the kinetics and thermodynamics of reactions, hydrodynamics, transport processes, and heat and mass transfer resistances in a chemical reactor.
This textbook describes the interaction of reacting molecules on the molecular scale and uses real-world examples to illustrate the principles of chemical reactor analysis and heterogeneous catalysis at every scale. It includes a strong focus on new approaches to process intensification, the modeling of multifunctional reactors, structured reactor types, and the importance of hydrodynamics and transport processes in a chemical reactor.
With end-of-chapter problem sets and multiple open-ended case studies to promote critical thinking, this book also offers supplementary online materials and an included instructor's manual. Readers will also find:
* A thorough introduction to the rate concept and species conservation equations in reactors, including chemical and flow reactors and the stoichiometric relations between reacting species
* A comprehensive exploration of reversible reactions and chemical equilibrium, including the thermodynamics of chemical reactions and different forms of the equilibrium constant
* Practical discussions of chemical kinetics and analysis of batch reactors, including batch reactor data analysis
* In-depth examinations of ideal flow reactors, CSTR, and plug flow reactor models
Ideal for undergraduate and graduate chemical engineering students studying chemical reactor engineering, chemical engineering kinetics, heterogeneous catalysis, and reactor design, Fundamentals of Chemical Reactor Engineering is also an indispensable resource for professionals and students in food, environmental, and materials engineering.
FUNDAMENTALS OF CHEMICAL REACTOR ENGINEERING
A comprehensive introduction to chemical reactor engineering from an industrial perspective
In Fundamentals of Chemical Reactor Engineering: A Multi-Scale Approach, a distinguished team of academics delivers a thorough introduction to foundational concepts in chemical reactor engineering. It offers readers the tools they need to develop a firm grasp of the kinetics and thermodynamics of reactions, hydrodynamics, transport processes, and heat and mass transfer resistances in a chemical reactor.
This textbook describes the interaction of reacting molecules on the molecular scale and uses real-world examples to illustrate the principles of chemical reactor analysis and heterogeneous catalysis at every scale. It includes a strong focus on new approaches to process intensification, the modeling of multifunctional reactors, structured reactor types, and the importance of hydrodynamics and transport processes in a chemical reactor.
With end-of-chapter problem sets and multiple open-ended case studies to promote critical thinking, this book also offers supplementary online materials and an included instructor's manual. Readers will also find:
* A thorough introduction to the rate concept and species conservation equations in reactors, including chemical and flow reactors and the stoichiometric relations between reacting species
* A comprehensive exploration of reversible reactions and chemical equilibrium, including the thermodynamics of chemical reactions and different forms of the equilibrium constant
* Practical discussions of chemical kinetics and analysis of batch reactors, including batch reactor data analysis
* In-depth examinations of ideal flow reactors, CSTR, and plug flow reactor models
Ideal for undergraduate and graduate chemical engineering students studying chemical reactor engineering, chemical engineering kinetics, heterogeneous catalysis, and reactor design, Fundamentals of Chemical Reactor Engineering is also an indispensable resource for professionals and students in food, environmental, and materials engineering.
A comprehensive introduction to chemical reactor engineering from an industrial perspective
In Fundamentals of Chemical Reactor Engineering: A Multi-Scale Approach, a distinguished team of academics delivers a thorough introduction to foundational concepts in chemical reactor engineering. It offers readers the tools they need to develop a firm grasp of the kinetics and thermodynamics of reactions, hydrodynamics, transport processes, and heat and mass transfer resistances in a chemical reactor.
This textbook describes the interaction of reacting molecules on the molecular scale and uses real-world examples to illustrate the principles of chemical reactor analysis and heterogeneous catalysis at every scale. It includes a strong focus on new approaches to process intensification, the modeling of multifunctional reactors, structured reactor types, and the importance of hydrodynamics and transport processes in a chemical reactor.
With end-of-chapter problem sets and multiple open-ended case studies to promote critical thinking, this book also offers supplementary online materials and an included instructor's manual. Readers will also find:
* A thorough introduction to the rate concept and species conservation equations in reactors, including chemical and flow reactors and the stoichiometric relations between reacting species
* A comprehensive exploration of reversible reactions and chemical equilibrium, including the thermodynamics of chemical reactions and different forms of the equilibrium constant
* Practical discussions of chemical kinetics and analysis of batch reactors, including batch reactor data analysis
* In-depth examinations of ideal flow reactors, CSTR, and plug flow reactor models
Ideal for undergraduate and graduate chemical engineering students studying chemical reactor engineering, chemical engineering kinetics, heterogeneous catalysis, and reactor design, Fundamentals of Chemical Reactor Engineering is also an indispensable resource for professionals and students in food, environmental, and materials engineering.
Inhaltsverzeichnis
Preface xiii
Foreword by Marc-Olivier Coppens xv
Foreword by Umit S. Ozkan xvii
About the Authors and Acknowledgments xix
List of Symbols xxi
About the Companion Website xxvii
1 Rate Concept and Species Conservation Equations in Reactors 1
1.1 Reaction Rates of Species in Chemical Conversions 1
1.2 Rate of a Chemical Change 3
1.3 Chemical Reactors and Conservation of Species 6
1.4 Flow Reactors and the Reaction Rate Relations 8
1.5 Comparison of Perfectly Mixed Flow and Batch Reactors 9
1.6 Ideal Tubular Flow Reactor 10
1.7 Stoichiometric Relations Between Reacting Species 13
1.7.1 Batch Reactor Analysis 13
1.7.2 Steady-Flow Analysis for a CSTR 13
1.7.3 Unsteady Perfectly Mixed-Flow Reactor Analysis 14
Problems and Questions 15
References 18
2 Reversible Reactions and Chemical Equilibrium 19
2.1 Equilibrium and Reaction Rate Relations 19
2.2 Thermodynamics of Chemical Reactions 21
2.3 Different Forms of Equilibrium Constant 23
2.4 Temperature Dependence of Equilibrium Constant and Equilibrium Calculations 25
Problems and Questions 33
References 34
3 Chemical Kinetics and Analysis of Batch Reactors 35
3.1 Kinetics and Mechanisms of Homogeneous Reactions 35
3.2 Batch Reactor Data Analysis 39
3.2.1 Integral Method of Analysis 41
3.2.1.1 First-Order Reaction 41
3.2.1.2 nth-Order Reaction and Method of Half-Lives 43
3.2.1.3 Overall Second-Order Reaction Between Reactants A and B 44
3.2.1.4 Second-Order Autocatalytic Reactions 48
3.2.1.5 Zeroth-Order Dependence of Reaction Rate on Concentrations 50
3.2.1.6 Data Analysis for a Reversible Reaction 51
3.2.2 Differential Method of Data Analysis 52
3.3 Changes in Total Pressure or Volume in Gas-Phase Reactions 54
Problems and Questions 56
References 61
4 Ideal-Flow Reactors: CSTR and Plug-Flow Reactor Models 63
4.1 CSTR Model 63
4.1.1 CSTR Data Analysis 67
4.2 Analysis of Ideal Plug-Flow Reactor 69
4.3 Comparison of Performances of CSTR and Ideal Plug-Flow Reactors 71
4.4 Equilibrium and Rate Limitations in Ideal-Flow Reactors 72
4.5 Unsteady Operation of Reactors 76
4.5.1 Unsteady Operation of a Constant Volume Stirred-Tank Reactor 76
4.5.2 Semi-batch Reactors 77
4.6 Analysis of a CSTR with a Complex Rate Expression 79
Problems and Questions 81
References 85
5 Multiple Reactor Systems 87
5.1 Multiple CSTRs Operating in Series 87
5.1.1 Graphical Method for Multiple CSTRs 91
5.2 Multiple Plug-Flow Reactors Operating in Series 93
5.3 CSTR and Plug-Flow Reactor Combinations 94
Problems and Questions 96
References 98
6 Multiple Reaction Systems 99
6.1 Selectivity and Yield Definitions 100
6.2 Selectivity Relations for Ideal Flow Reactors 101
6.3 Design of Ideal Reactors and Product Distributions for Multiple Reaction Systems 104
6.3.1 Parallel Reactions 104
6.3.2 Consecutive Reactions 110
Problems and Questions 113
References 116
7 Heat Effects and Non-isothermal Reactor Design 117
7.1 Heat Effects in a Stirred-Tank Reactor 118
7.2 Steady-State Multiplicity in a CSTR 121
7.3 One-Dimensional Energy Balance for a Tubular Reactor 126
7.4 Heat Effects in Multiple Reaction Systems 131
&nb
Foreword by Marc-Olivier Coppens xv
Foreword by Umit S. Ozkan xvii
About the Authors and Acknowledgments xix
List of Symbols xxi
About the Companion Website xxvii
1 Rate Concept and Species Conservation Equations in Reactors 1
1.1 Reaction Rates of Species in Chemical Conversions 1
1.2 Rate of a Chemical Change 3
1.3 Chemical Reactors and Conservation of Species 6
1.4 Flow Reactors and the Reaction Rate Relations 8
1.5 Comparison of Perfectly Mixed Flow and Batch Reactors 9
1.6 Ideal Tubular Flow Reactor 10
1.7 Stoichiometric Relations Between Reacting Species 13
1.7.1 Batch Reactor Analysis 13
1.7.2 Steady-Flow Analysis for a CSTR 13
1.7.3 Unsteady Perfectly Mixed-Flow Reactor Analysis 14
Problems and Questions 15
References 18
2 Reversible Reactions and Chemical Equilibrium 19
2.1 Equilibrium and Reaction Rate Relations 19
2.2 Thermodynamics of Chemical Reactions 21
2.3 Different Forms of Equilibrium Constant 23
2.4 Temperature Dependence of Equilibrium Constant and Equilibrium Calculations 25
Problems and Questions 33
References 34
3 Chemical Kinetics and Analysis of Batch Reactors 35
3.1 Kinetics and Mechanisms of Homogeneous Reactions 35
3.2 Batch Reactor Data Analysis 39
3.2.1 Integral Method of Analysis 41
3.2.1.1 First-Order Reaction 41
3.2.1.2 nth-Order Reaction and Method of Half-Lives 43
3.2.1.3 Overall Second-Order Reaction Between Reactants A and B 44
3.2.1.4 Second-Order Autocatalytic Reactions 48
3.2.1.5 Zeroth-Order Dependence of Reaction Rate on Concentrations 50
3.2.1.6 Data Analysis for a Reversible Reaction 51
3.2.2 Differential Method of Data Analysis 52
3.3 Changes in Total Pressure or Volume in Gas-Phase Reactions 54
Problems and Questions 56
References 61
4 Ideal-Flow Reactors: CSTR and Plug-Flow Reactor Models 63
4.1 CSTR Model 63
4.1.1 CSTR Data Analysis 67
4.2 Analysis of Ideal Plug-Flow Reactor 69
4.3 Comparison of Performances of CSTR and Ideal Plug-Flow Reactors 71
4.4 Equilibrium and Rate Limitations in Ideal-Flow Reactors 72
4.5 Unsteady Operation of Reactors 76
4.5.1 Unsteady Operation of a Constant Volume Stirred-Tank Reactor 76
4.5.2 Semi-batch Reactors 77
4.6 Analysis of a CSTR with a Complex Rate Expression 79
Problems and Questions 81
References 85
5 Multiple Reactor Systems 87
5.1 Multiple CSTRs Operating in Series 87
5.1.1 Graphical Method for Multiple CSTRs 91
5.2 Multiple Plug-Flow Reactors Operating in Series 93
5.3 CSTR and Plug-Flow Reactor Combinations 94
Problems and Questions 96
References 98
6 Multiple Reaction Systems 99
6.1 Selectivity and Yield Definitions 100
6.2 Selectivity Relations for Ideal Flow Reactors 101
6.3 Design of Ideal Reactors and Product Distributions for Multiple Reaction Systems 104
6.3.1 Parallel Reactions 104
6.3.2 Consecutive Reactions 110
Problems and Questions 113
References 116
7 Heat Effects and Non-isothermal Reactor Design 117
7.1 Heat Effects in a Stirred-Tank Reactor 118
7.2 Steady-State Multiplicity in a CSTR 121
7.3 One-Dimensional Energy Balance for a Tubular Reactor 126
7.4 Heat Effects in Multiple Reaction Systems 131
&nb
Details
| Erscheinungsjahr: | 2021 |
|---|---|
| Genre: | Chemie |
| Rubrik: | Naturwissenschaften & Technik |
| Medium: | Buch |
| Inhalt: | 352 S. |
| ISBN-13: | 9781119755890 |
| ISBN-10: | 1119755891 |
| Sprache: | Englisch |
| Herstellernummer: | 1W119755890 |
| Autor: |
Dogu, Timur
Dogu, Gulsen |
| Auflage: | 1. Auflage |
| Hersteller: |
Wiley
Wiley & Sons |
| Maße: | 24 x 170 x 284 mm |
| Von/Mit: | Timur Dogu (u. a.) |
| Erscheinungsdatum: | 29.10.2021 |
| Gewicht: | 0,816 kg |
Inhaltsverzeichnis
Preface xiii
Foreword by Marc-Olivier Coppens xv
Foreword by Umit S. Ozkan xvii
About the Authors and Acknowledgments xix
List of Symbols xxi
About the Companion Website xxvii
1 Rate Concept and Species Conservation Equations in Reactors 1
1.1 Reaction Rates of Species in Chemical Conversions 1
1.2 Rate of a Chemical Change 3
1.3 Chemical Reactors and Conservation of Species 6
1.4 Flow Reactors and the Reaction Rate Relations 8
1.5 Comparison of Perfectly Mixed Flow and Batch Reactors 9
1.6 Ideal Tubular Flow Reactor 10
1.7 Stoichiometric Relations Between Reacting Species 13
1.7.1 Batch Reactor Analysis 13
1.7.2 Steady-Flow Analysis for a CSTR 13
1.7.3 Unsteady Perfectly Mixed-Flow Reactor Analysis 14
Problems and Questions 15
References 18
2 Reversible Reactions and Chemical Equilibrium 19
2.1 Equilibrium and Reaction Rate Relations 19
2.2 Thermodynamics of Chemical Reactions 21
2.3 Different Forms of Equilibrium Constant 23
2.4 Temperature Dependence of Equilibrium Constant and Equilibrium Calculations 25
Problems and Questions 33
References 34
3 Chemical Kinetics and Analysis of Batch Reactors 35
3.1 Kinetics and Mechanisms of Homogeneous Reactions 35
3.2 Batch Reactor Data Analysis 39
3.2.1 Integral Method of Analysis 41
3.2.1.1 First-Order Reaction 41
3.2.1.2 nth-Order Reaction and Method of Half-Lives 43
3.2.1.3 Overall Second-Order Reaction Between Reactants A and B 44
3.2.1.4 Second-Order Autocatalytic Reactions 48
3.2.1.5 Zeroth-Order Dependence of Reaction Rate on Concentrations 50
3.2.1.6 Data Analysis for a Reversible Reaction 51
3.2.2 Differential Method of Data Analysis 52
3.3 Changes in Total Pressure or Volume in Gas-Phase Reactions 54
Problems and Questions 56
References 61
4 Ideal-Flow Reactors: CSTR and Plug-Flow Reactor Models 63
4.1 CSTR Model 63
4.1.1 CSTR Data Analysis 67
4.2 Analysis of Ideal Plug-Flow Reactor 69
4.3 Comparison of Performances of CSTR and Ideal Plug-Flow Reactors 71
4.4 Equilibrium and Rate Limitations in Ideal-Flow Reactors 72
4.5 Unsteady Operation of Reactors 76
4.5.1 Unsteady Operation of a Constant Volume Stirred-Tank Reactor 76
4.5.2 Semi-batch Reactors 77
4.6 Analysis of a CSTR with a Complex Rate Expression 79
Problems and Questions 81
References 85
5 Multiple Reactor Systems 87
5.1 Multiple CSTRs Operating in Series 87
5.1.1 Graphical Method for Multiple CSTRs 91
5.2 Multiple Plug-Flow Reactors Operating in Series 93
5.3 CSTR and Plug-Flow Reactor Combinations 94
Problems and Questions 96
References 98
6 Multiple Reaction Systems 99
6.1 Selectivity and Yield Definitions 100
6.2 Selectivity Relations for Ideal Flow Reactors 101
6.3 Design of Ideal Reactors and Product Distributions for Multiple Reaction Systems 104
6.3.1 Parallel Reactions 104
6.3.2 Consecutive Reactions 110
Problems and Questions 113
References 116
7 Heat Effects and Non-isothermal Reactor Design 117
7.1 Heat Effects in a Stirred-Tank Reactor 118
7.2 Steady-State Multiplicity in a CSTR 121
7.3 One-Dimensional Energy Balance for a Tubular Reactor 126
7.4 Heat Effects in Multiple Reaction Systems 131
&nb
Foreword by Marc-Olivier Coppens xv
Foreword by Umit S. Ozkan xvii
About the Authors and Acknowledgments xix
List of Symbols xxi
About the Companion Website xxvii
1 Rate Concept and Species Conservation Equations in Reactors 1
1.1 Reaction Rates of Species in Chemical Conversions 1
1.2 Rate of a Chemical Change 3
1.3 Chemical Reactors and Conservation of Species 6
1.4 Flow Reactors and the Reaction Rate Relations 8
1.5 Comparison of Perfectly Mixed Flow and Batch Reactors 9
1.6 Ideal Tubular Flow Reactor 10
1.7 Stoichiometric Relations Between Reacting Species 13
1.7.1 Batch Reactor Analysis 13
1.7.2 Steady-Flow Analysis for a CSTR 13
1.7.3 Unsteady Perfectly Mixed-Flow Reactor Analysis 14
Problems and Questions 15
References 18
2 Reversible Reactions and Chemical Equilibrium 19
2.1 Equilibrium and Reaction Rate Relations 19
2.2 Thermodynamics of Chemical Reactions 21
2.3 Different Forms of Equilibrium Constant 23
2.4 Temperature Dependence of Equilibrium Constant and Equilibrium Calculations 25
Problems and Questions 33
References 34
3 Chemical Kinetics and Analysis of Batch Reactors 35
3.1 Kinetics and Mechanisms of Homogeneous Reactions 35
3.2 Batch Reactor Data Analysis 39
3.2.1 Integral Method of Analysis 41
3.2.1.1 First-Order Reaction 41
3.2.1.2 nth-Order Reaction and Method of Half-Lives 43
3.2.1.3 Overall Second-Order Reaction Between Reactants A and B 44
3.2.1.4 Second-Order Autocatalytic Reactions 48
3.2.1.5 Zeroth-Order Dependence of Reaction Rate on Concentrations 50
3.2.1.6 Data Analysis for a Reversible Reaction 51
3.2.2 Differential Method of Data Analysis 52
3.3 Changes in Total Pressure or Volume in Gas-Phase Reactions 54
Problems and Questions 56
References 61
4 Ideal-Flow Reactors: CSTR and Plug-Flow Reactor Models 63
4.1 CSTR Model 63
4.1.1 CSTR Data Analysis 67
4.2 Analysis of Ideal Plug-Flow Reactor 69
4.3 Comparison of Performances of CSTR and Ideal Plug-Flow Reactors 71
4.4 Equilibrium and Rate Limitations in Ideal-Flow Reactors 72
4.5 Unsteady Operation of Reactors 76
4.5.1 Unsteady Operation of a Constant Volume Stirred-Tank Reactor 76
4.5.2 Semi-batch Reactors 77
4.6 Analysis of a CSTR with a Complex Rate Expression 79
Problems and Questions 81
References 85
5 Multiple Reactor Systems 87
5.1 Multiple CSTRs Operating in Series 87
5.1.1 Graphical Method for Multiple CSTRs 91
5.2 Multiple Plug-Flow Reactors Operating in Series 93
5.3 CSTR and Plug-Flow Reactor Combinations 94
Problems and Questions 96
References 98
6 Multiple Reaction Systems 99
6.1 Selectivity and Yield Definitions 100
6.2 Selectivity Relations for Ideal Flow Reactors 101
6.3 Design of Ideal Reactors and Product Distributions for Multiple Reaction Systems 104
6.3.1 Parallel Reactions 104
6.3.2 Consecutive Reactions 110
Problems and Questions 113
References 116
7 Heat Effects and Non-isothermal Reactor Design 117
7.1 Heat Effects in a Stirred-Tank Reactor 118
7.2 Steady-State Multiplicity in a CSTR 121
7.3 One-Dimensional Energy Balance for a Tubular Reactor 126
7.4 Heat Effects in Multiple Reaction Systems 131
&nb
Details
| Erscheinungsjahr: | 2021 |
|---|---|
| Genre: | Chemie |
| Rubrik: | Naturwissenschaften & Technik |
| Medium: | Buch |
| Inhalt: | 352 S. |
| ISBN-13: | 9781119755890 |
| ISBN-10: | 1119755891 |
| Sprache: | Englisch |
| Herstellernummer: | 1W119755890 |
| Autor: |
Dogu, Timur
Dogu, Gulsen |
| Auflage: | 1. Auflage |
| Hersteller: |
Wiley
Wiley & Sons |
| Maße: | 24 x 170 x 284 mm |
| Von/Mit: | Timur Dogu (u. a.) |
| Erscheinungsdatum: | 29.10.2021 |
| Gewicht: | 0,816 kg |
Warnhinweis